Inerting, purging and blanketing gases
Processes to clear potentially flammable, explosive or toxic materials from tanks, lines and other areas or to control the atmosphere within them are important operational steps for many industries.
Coregas has supplied gases for these processes across Australian industry throughout our 40+ years of operation, which has led to our standard range including gases suitable for most inerting, purging and blanketing applications. Whether controlling fire and explosion hazards such as combustible dusts, eliminating toxic materials or controlling product quality during production, we have a gas to suit.
For non-standard applications, Coregas can produce customised gases or gas mixtures, supply in bulk or design and install complete supply systems. Our engineering and technical teams have decades of experience in delivering bespoke systems customised exactly to individual applications’ requirements. See our case study below for one example of a specially designed mining inerting project.
Inerting and purging refer to replacing the atmosphere in a line, vessel or other area with an inert atmosphere, eg the space above liquid fuel in a fuel tank, to reduce the likelihood of combustion. Purging of supply lines, pipelines and tanks is a common step before commencing production or prior to shutdown.
Blanketing refers to maintaining a protective, inert layer over materials. Blanketing is commonly used in storage of highly volatile or reactive substances, or where there are concerns around safety or degradation of the substance if it is not protected from moisture or oxidation.
Combustion requires oxygen, fuel and an ignition source such as heat; reducing just one of these will prevent combustion. Whilst it may not be possible to remove fuel and heat from an area such as a fuel tank, replacing air above the fuel with an inert gas reduces oxygen well below the concentration required for combustion.
The most common gas used for inerting, purging and blanketing is nitrogen, due to its cost effectiveness, ease of production and relative safety. It is so common, the processes are also known as nitrogen inerting, nitrogen purging and nitrogen blanketing respectively.
Typical applications include inerting of fuel tanks, oil tanker cargo holds, mines, chemical industry, petrochemicals, refinery and food packaging.
Long-wall mining, where a machine extracts coal from a coal seam and the resulting void is allowed to collapse in on itself as the machine moves on, is potentially hazardous. During mining, coal releases methane which can build up in the collapsed area known as the goaf. Mixed with oxygen in air, this methane can produce a highly explosive mixture that has historically resulted in many deaths and injuries.
While the long wall is still in operation, constantly flushing the goaf with fresh air ensures miners can breathe and prevents a build-up of methane and toxic gases. When extraction ends however, the area must be sealed and, to ensure the atmosphere remains safe, filled with inert gas to displace oxygen.
One such Rio Tinto mine in Queensland uses the long-wall mining method and awarded Coregas the contract to supply liquid nitrogen for their long wall inertisation.
Previously the mine made inert gas on site using generators such as boilers or jet engines, but with Coregas’ air separation units (ASUs) in Mackay and Port Kembla, nitrogen is in plentiful supply.
The mine chose to use liquid nitrogen because of its benefits of being a flexible, more reliable alternative to the previous on-site generators. Plus it came with the environmental advantage of not using diesel fuel and the expertise of Coregas’ engineering and technical teams.
Coregas’ large capacity for nitrogen supply proved useful because a long wall is typically 415 metres wide, 2.5-3.0 metres high and 4 kilometres in length. That requires a lot of gas to fill. In this case, it took 25 days of work with the facility manned 24/7 and many loads of liquid nitrogen.
The Mine Ventilation Engineer was very pleased with the outcome, commenting that “nitrogen is the way to go in future”.
The success of the project led to it being presented to a mine ventilation conference in 2017 and published in the conference proceedings:
Caley, D, (2017). Using liquid nitrogen for the inertisation of goafs. In The Australian Mine Ventilation Conference. Brisbane QLD, 30 August 2017. The Australian Institute of Minerals and Metallurgy. pp35-39.
The curing process for paints, varnish and other coatings is often triggered by oxygen or moisture from the air. Paints and coatings are stored in cans and drums where there is inevitably a small head space of gas above the paint. During packaging, the cans are filled with an inert gas in the head space to avoid the formation of a crust at the surface of the liquid in the can due to a curing reaction with air. As an example, oxygen-cured systems such as alkyds (drying oils) are generally canned using controlled atmosphere packaging.
Traditionally, nitrogen has been used for this controlled atmosphere packaging. The use of argon in high value paints and modern packaging processes is now becoming increasingly popular, due to its heavier weight than oxygen meaning that it forms a more effective inert layer over the paint.
After paint cans are opened it is also possible to prolong their storage life by purging the head space over the paint with inert argon gas. Some paint shops use cylinder argon for this purpose. Smaller hobby users can also purchase specialised aerosol cans containing pure argon to squirt this gas into the top of the can to create an inert head space and prolong storage life. The range of applications for these products is as broad as varnish, paint, polyurethane glue, oil based wood finishes, auto body coatings and photographic developing chemicals.